To configure Outlook Web Access to allow content that is equal to the size of the maximum message size on a Windows Server 2008-based computer
appcmd set config "Default Web Site/owa" -section:requestFiltering -requestLimits.maxAllowedContentLength:<Content_Length_In_Kilobytes>
<Content_Length_In_Kilobytes> is wrong.
This should be :<Content_Length_In_bytes>