The path to the XSD file is slightly different in SQL Server 2008. In the path listed above it says '90' it should read '100'. This is the correct path to the XSD file:
\Microsoft SQL Server\100\Tools\Binn\schemas\sqlserver\2004\07\showplan\showplanxml.xsd
Gail Erickson [MSFT]: Thanks for reporting this oversight. The topic will be corrected in the next update to Books Online (end of April 2009).